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    Chemoselective aerobic oxidation of aliphatic alcohols in lignin in micellar system

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    Lignin-block copolymer as nanoreactors in aqueous effluent (584.1Kb)
    Date
    2016-05
    Author
    Azadfar, Mohammadali
    Hiscox, William C.
    Chen, Shulin
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    Abstract
    A micellar catalytic system for chemoselective aerobic oxidation of primary alcohol in the diol fragment guaiacylglycerol-guaiacyl ether as one of the most common structure in lignin has been proposed. The catalyst system consists of TEMPO/Cu (II), mediated by oxygen gas. Our studies highlight the prospect of combining this method with a PEO-PPO-PEO micellar system in basic aqueous effluent of delignification processes of lignocellulosic materials to achieve the oxidation of primary alcohol to aldehyde.
    URI
    http://hdl.handle.net/2376/11908
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    • Washington State University Academic Showcase 2017
    • Chen, Shulin