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Localized Chemistry of 99Tc in Simulated Low Activity Waste Glass
(2016)
A priority of the United States Department of Energy (DOE) is to dispose of the nuclear waste accumulated in the underground tanks at the Hanford Nuclear Reservation in Richland, WA. Incorporation and stabilization of ...
Separation and Identification of Metal Ions via Ligand Assisted Capillary Electrophoresis
(2013)
Capillary electrophoresis (CE) is a powerful tool for analytical separations. These separations are achieved based on analyte charge and size, allowing for the simultaneous separation and detection of positive, negative ...
Activation Product Analysis in the Presence of Fission Products
(2015)
Methods to quantify activation products in complex samples are needed in areas such as nuclear safeguards, waste treatment and identification, environmental monitoring, and consequence management. Formation of activation ...
Application of the asymmetric [C+NC+CC] coupling reaction to synthesis
(2013)
The asymmetric [C+NC+CC] coupling reaction provides stereoselective access to highly functionalized pyrrolidine rings. The hallmark of this azomethine ylide cycloaddition cascade is the ability to successfully employ ...
NEW METHODS FOR THE CONVERGENT GLYCOLIGATION OF PEPTIDES
(2015)
The attachment of oligosaccharides (glycans) to proteins is an important co- and post-translational modification which greatly expands the functional and structural diversity of a proteome. As glycosylation is integral to ...
DEVELOPMENT OF NOVEL REACTIVE SULFUR SPECIES DONORS
(2018)
Reactive sulfur species are important cell signaling molecules. Among them, hydrogen sulfide (H2S), hydrogen polysulfides (H2Sn, n>1), persulfides (RSSH), and S-nitroso hydrogen sulfide (HSNO) are believed to be mediators ...
Novel Instrumental Approaches to Ion Mobility Spectrometry: Voltage-Sweep, High-Pressure, and Radiative-Ion-Ion-Recombination
(2012)
Ion Mobility Spectrometry (IMS) provides reliable and fast detection in a multitude of worldwide environments. Many IMS systems are used in security applications where IMS's ability to rapidly detect explosives and narcotics ...
Using Raman Spectroscopy to Probe the Internal Structure and Excitonic Properties of Light-Harvesting Aggregates of Tetra(sulfonatophenyl)porphyrin
(2013)
Borrowing ideas from light-harvesting aggregates in nature for use in photovoltaics or solar fuels to improve light collection and solar energy efficiency is an attractive prospect. However an incomplete understanding of ...
Development and applications of relativistic correlation consistent basis sets for lanthanide elements and accurate ab initio thermochemistry and spectroscopy
(2017)
The relativistic correlation consistent basis sets for Lanthanide elements are developed with the 3rd-order Douglas-Kroll-Hess Hamiltonian. Atomic and molecular benchmark calculations show robust reliability of the new ...
UTILIZATION OF TRADITIONAL AND NOVEL NMR SPECTROSCOPIC TECHNIQUES TO PROBE INTERACTIONS IN THE ORGANIC PHASE OF LIQUID-LIQUID SOLVENT EXTRACTION SYSTEMS
(2017)
Solvent extraction is a technique commonly used is the reprocessing of used nuclear fuel elements. It utilizes the partitioning of a metal ion between two immiscible phases, typically an acidic aqueous phase and a light ...