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TECHNETIUM (IV) COMPLEXATION CHEMISTRY WITH POLYAMINO POLYCARBOXYLATE LIGANDS
99Technetium (t½ = 2.1×105 y) constitutes approximately 6.1% of the cumulative yield of thermal 235U thermal fission. In the +7 oxidation state, technetium has high aqueous solubility and forms the anionic structure TcO4- ...
Complexation of Tetravalent Fission Products and Plutonium(IV) with Polyaminopolycarboxylate Ligands
Management of problematic tetravalent fission products and actinides present in the back end of the nuclear fuel cycle presents important scientific and technical challenges concerning the reprocessing and disposal of used ...
Tc(IV) complexation with organic ligands
99Technetium poses a difficult problem at multiple Department of Energy sites, where there are currently vast quantities in storage. 99Tc has a half-life of 2.3 x 105 years, thus it will have to be accounted for a very ...